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Matthew Green

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School for Engineering of Matter, Transport and Energy
Assoc Professor
Faculty, TEMPE Campus, Mailcode 6106
Biography: 

Matthew Green is currently an Associate Professor with tenure within Chemical Engineering at ASU. He joined the faculty at ASU in 2014 as an assistant professor. His research is focused on the design and synthesis of novel, ion-containing polymers to be used in applications such as water purification, carbon dioxide capture, nanocomposites, and micellar solution assemblies. He obtained bachelor’s degrees in chemical engineering and chemistry (2007), and a doctorate in chemical engineering at Virginia Tech working with Prof. Timothy Long (2011). Then, he worked as a postdoctoral researcher at the University of Delaware in the Chemical and Biomolecular Engineering Department with professors Thomas Epps, III and Millicent Sullivan.

https://faculty.engineering.asu.edu/green

Education: 
  • Ph.D. Chemical Engineering, Virginia Tech 2011
  • B.S. Chemistry, Virginia Tech 2007
  • B.S. Chemical Engineering, Virginia Tech 2007
Research Website URL: 
http://faculty.engineering.asu.edu/green/
Google Scholar URL: 
Google Scholar Profile
Research Interests: 

We are focused on integrating macromolecular design with controlled synthesis techniques to produce hierarchical and multifunctional materials. In particular, we are interested in understanding the interplay between electrostatic or Coulombic interactions and microstructure, inter-phase interactions, thermomechanical properties, and transport. Our current research thrusts include: 1) designing chlorine-tolerant, fouling-resistant membranes for osmotically driven water purification and supported ionic liquid membranes for CO2 capture, 2) developing innovative matrix chemistries and stimuli-responsive behavior for epoxy thermosets and nanocomposites, 3) analyzing the ability of phase-separated ionomers to template nanoparticle location, 4) directing the solution assembly of amphiphilic ionomers and controlling functional group presentation on their surfaces, 5) tailoring the surface activity of electrospun fibers and silicone surfactants, and 6) studying the polymer microphase separation of ion-containing block polymers.

Publications: 

  1. Mather, B.D.; Baker, M.B.; Beyer, F.L.; Berg, M.A.G.; Green, M.D.; Long, T.E. Supramolecular Triblock Copolymers Containing Complementary Nucleobase Molecular Recognition. Macromolecules 2007, 40 (19), 6834–6845.

  2. Mather, B.D.; Baker, M.B.; Beyer, F.L.; Green, M.D.; Berg, M.A.G.; Long, T.E. Multiple Hydrogen Bonding for the Noncovalent Attachment of Ionic Functionality in Triblock Copolymers. Macromolecules 2007, 40 (13), 4396–4398.
  3. Layman, J.M.; Ramirez, S.M.; Green, M.D.; Long, T.E., Influence of Polycation Molecular Weight on Poly(2-dimethylaminoethyl methacrylate)-Mediated DNA Delivery In Vitro. Biomacromolecules 2009, 10 (5), 1244-1252.
  4. Green, M. D.; Long, T. E., Designing Imidazole-Based Ionic Liquids and Ionic Liquid Monomers for Emerging Technologies. Polymer Reviews 2009, 49 (4), 291 - 314.
  5. Green, M. D.; Allen Jr, M. H.; Dennis, J. M.; Cruz, D. S.-d. l.; Gao, R.; Winey, K. I.; Long, T. E., Tailoring macromolecular architecture with imidazole functionality: A perspective for controlled polymerization processes. European Polymer Journal 2011, 47 (4), 486-496.
  6. Allen Jr., M. H.; Green, M. D.; Getaneh, H.; Miller, K.; Long, T. E., Tailoring Charge Density and Hydrogen Bonding of Imidazolium Copolymers for Efficient Gene Delivery. Biomacromolecules 2011, 12 (6), 2243-2250.
  7. Green, M. D.; Schreiner, C.; Long, T. E., Thermal, Rheological, and Ion-Transport Properties of Phosphonium-Based Ionic Liquids. The Journal of Physical Chemistry A 2011, 115 (47), 13829-13835.
  8. Green, M. D.; Salas-de la Cruz, D.; Ye, Y.; Layman, J. M.; Elabd, Y. A.; Winey, K. I.; Long, T. E., Alkyl-Substituted N-Vinylimidazolium Polymerized Ionic Liquids: Thermal Properties and Ionic Conductivities. Macromolecular Chemistry and Physics 2011, 212 (23), 2522-2528.
  9. Salas-de la Cruz, D.; Green, M. D.; Ye, Y.; Elabd, Y. A.; Long, T. E.; Winey, K. I., Correlating backbone-to-backbone distance to ionic conductivity in amorphous polymerized ionic liquids. Journal of Polymer Science Part B: Polymer Physics 2011, 50 (5), 338-346.
  10. Hemp, S. T.; Allen, M. H.; Green, M. D.; Long, T. E., Phosphonium-Containing Polyelectrolytes for Nonviral Gene Delivery. Biomacromolecules 2011, 13 (1), 231-238.
  11. Green, M. D.; Choi, J.-H.; Winey, K. I.; Long, T. E., Synthesis of Imidazolium-Containing ABA Triblock Copolymers: Role of Charge Placement, Charge Density, and Ionic Liquid Incorporation. Macromolecules 2012, 45, 4749.
  12. Green, M. D.; Wang, D.; Hemp, S. T.; Choi, J.-H.; Winey, K. I.; Heflin, J. R.; Long, T. E., Synthesis of imidazolium ABA triblock copolymers for electromechanical transducers. Polymer 2012, 53 (17), 3677-3686.
  13. Green, M. D.; Foster, A. A.; Roy, R.; Lehr, R. M.; Epps, T. H., III; Sullivan, M. O., Catch and Release: Photocleavable Cationic Diblock Copolymers as a Potential Platform for Nucleic Acid Delivery. Polymer Chemistry 2014, 5 (19), 5535–5541.
  14. Foster, A. A.; Greco, C.; Green, M. D.; Epps, T. H., III; Sullivan, M. O., Light-Mediated Activation of siRNA Binding and Release in Diblock Copolymer Assemblies for Controlled Gene Silencing. Advanced Healthcare Materials 2014, 4 (5), 760–770.
  15. Heckenbach, M. E.; Romero, F. N.; Green, M. D.; Halden, R. U., Meta-Analysis of Ionic Liquid Literature and Toxicology. Chemosphere, 2016, 150, 266–274.
  16. Wang, D.; Green, M.D.; Chen, K.; Daengngam, C.; Kotsuchibashi, Y., Stimuli-Responsive Polymers: Design, Synthesis, Characterization, and Applications. International Journal of Polymer Science, 2016, 2016 (2016), 1–2. **editorial
  17. Schreiner, C.; Bridge, A. T.; Hunley, M. T.; Long, T. E.; Green, M. D. Segmented Imidazolium Ionenes: Solution Rheology, Thermomechanical Properties, and Electrospinning. Polymer, 2017, 114 (2017), 257–265.
  18. Quinn, J. A.; Yang, Y.; Buffington, A. N.; Romero, F. N.; Green, M. D. Preparation and Characterization of Crosslinked Electrospun poly(vinyl alcohol) Nanofibrous Membranes. Polymer, 2018, 134 (2018), 275–281.
  19. Hong, H.; Tronstad, Z. T.; Yang, Y.; Green, M. D. Characterization of PVC-soy protein nonwoven mats prepared by electrospinning. AIChE Journal, 2018, 64(7), 2737–2744.
  20. Wang, M.; Dheressa, E. Brown, K. A.; Green, M. D. Effect of Crosslinker Length and Architecture on the Thermomechanical properties of CNT-loaded Elastomeric Polymer Matrix Composites. Macromolecular Rapid Communications, 2018, 39, 1800091. **Invited article as part of a special issue highlighting “Young Talents.”
  21. Yang, Y.; Ramos, T. L.; Heo, Jihun; Green, M.D. Zwitterionic poly(arylene ether sulfone) copolymer/Poly(arylene ether sulfone) blends for fouling-resistant desalination membranes. Journal of Membrane Science, 2018, 561(2018), 69­–78.
  22. Agarwal, A.; Qin, Y.; Chen, B.; Blei, M.; Wu, K.; Liu, L.; Shen, Y.; Wright, D.; Green, M. D.; Zhuang, H.; Tongay, S. Anomalous Isoelectronic Chalcogen Rejection in 2D Anisotropic vdW TiS3(1-x)Se3x Trichalcogenides. Nanoscale, 2018, 10, 15654–15660.
  23. Kelkar, V. P.; Pant, A.; Rolsky, C. B.; Green, M. D.; Tongay, S.; Halden, R. U. Chemical and Physical Changes of Microplastics During Sterilization by Chlorination. Water Research, 2019, 163(2019), 114871.
  24. Hocken, A.; Yang, Y.; Beyer, F. L.; Morgan, B. F.; Kline, K.; Piper, T.; Green, M. D. Photocurable poly(ethylene glycol) diacrylate resins with variable silica nanoparticle loading. Industrial & Engineering Chemistry Research, 2019, 58(32), 14775–14784. **Invited article, part of a special issue on the “2019 Class of Influential Researchers”
  25. Kong, W.; Wang, Z.; Wang, M.; Manning, K. C.; Uppal, A.; Green, M. D.; Wang, R. Y.; Rykaczewski, K. Oxide-mediated formation of chemically stable tungsten-liquid metal mixtures for enhanced thermal interfaces. Advanced Materials, 2019, 1904309.
  26. Tran, M.; Kline, K.; Qin, Y.; Shen, Y.; Green, M. D.; Tongay, S. 2D coordination polymers: Design guidelines and materials perspective. Applied Physics Reviews, 2019, 6(4), 041311.
  27. Dai, R.; Wang, M.; Wang, D.; Hu, Z.; Green, M. D.; Nian, Q. Understanding Mechanical Behavior of Metallic Foam with Hollow Struts Using Pentagonal Dodecahedron Model. Scripta Materialia, 2020, 182, 114–119.
  28. Yin, H.; Cay-Durgan, P.; Lai, T.; Zhu, G.; Engebretson, K.; Setiadji, R.; Green, M. D.; Lind, M. L. Effect of ZIF-71 ligand-exchange surface modification on biofuel recovery through pervaporation. Polymer, 2020, 195(2020), 122379.
  29. Gupta, S.; Singh, P.; Moghadas, B.; Grim, B. J.; Kodibagkar, V.D.; Green, M. D. Synthesis of PEG and quaternary ammonium grafted silicone copolymers as nanoemulsifiers. ACS Applied Polymer Materials, 2020, 2(5), 1856–1864.
  30. de Oliveira, C.; Khatua, B.; El-Kurdi, B.; Patel, K.; Mishra, V.; Navina, S.; Grim, B. J.; Gupta, S.; Cherry, B. R.; Belohlavek, M.; Yarger, J. L.; Green, M. D.; Singh, V. P. Thermodynamic interference with bile acid demicelleization reduces systemic entry and injury during cholestasis. Scientific Reports, 2020, 10(1), 1–14.
  31. Mangal, J. L.; Inamdar, S.; Yang, Y.; Shi, X.; Wankhede, M.; Gu, H.; Rege, K.; Green, M. D.; Curtis, M.; Acharya, A. P. Metabolite releasing polymers control dendritic cell function by modulating their energy metabolism. Journal of Materials Chemistry B, 2020, 8, 5195–5203.
  32. Thomas, E. R.; Jain, A.; Mann, S. C.; Yang, Y.; Green, M. D.; Walker, W. S.; Perrault, F.; Lind, M. L.; Verduzco, R. Freestanding self-assembled sulfonated pentablock terpolymer membranes for high flux pervaporation desalination. Journal of Membrane Science, 2020, 613, 118460.
  33. Korah, M. M.; Nori, T.; Tongay, S.; Green, M. D. Harnessing biological applications of quantum materials: opportunities and precautions. Journal of Materials Chemistry C, 2020, 8, 10498–10525. **Part of the 2020 Emerging Investigators online collection
  34. Yang, Y.; Muhich, C. L.; Green, M. D. Kinetics and mechanisms of polycondensation reactions between aryl halides and bisphenol A. Polymer Chemistry, 2020, 11, 5078–5087. **Part of the 2021 Pioneering Investigator Special Issue
  35. Wang, M.; Schwindt, A. E.; Wu, K.; Qin, Y.; Kwan, A.; Tongay, S.; Green, M. D. Damage Detection through Förster Resonance Energy Transfer in Mechanoresponsive Polymer Nanocomposites. Polymer, 2021, (212), 123275.
  36. Mithaiwala, H.; Tronstad, Z. T.; Modayil Korah, M.; Buffington, A.; Green, M. D. Crosslinked Electrospun Composite Membranes of Poly(vinyl alcohol) and Poly(vinyl chloride): Tunable Mechanical Properties, Porosity, and Performance. Polymer International, 2021, Accepted.
  37. Lee, J.; Hocken, A.; Green, M. D. Advances in the Molecular Design of Ionenes for a Diverse Range of Applications. Molecular Systems Design & Engineering, 2021, Accepted.
  38. Yousaf, A.; Gilliam, M. S.; Chang, S. L. Y.; Augustin, M.; Guo, Y.; Tahir, F.; Wang, M.; Schwindt, A.; Chu, X. S.; Li, D. O.; Kale, S.; Debnath, A.; Liu, Y.; Green, M. D.; Santos, E. J. G.; Green, A. A.; and Wang., Q. H. Exfoliation of Two-Dimensional Nanosheets of Metal Diborides. The Journal of Physical Chemistry C, 2021, Accepted.
Research Activity: 

  • Lead PI

    1.2015 Defense University Research Instrumentation Program (DURIP) – “Materials discovery: Characterization equipment to catalyze innovation in materials design.”  Co-PIs: Aditi Chattopadhyay, Lenore Dai, Mary Laura Lind, 09/01/2015 – 08/31/2016

    2.2016 ARO STIR – “Mechanoresponsive polymer-matrix composites.” 05/01/2016 – 01/31/2017

    3.2017 Defense University Research Instrumentation Program (DURIP) – “Catalyzing Material Discovery Through Electrochemical and Porosity Analysis.”  Co-PIs: Jerry Lin, César Torres, 09/01/2017 – 08/31/2018

    4.2018 Department of Defense Seed Grant – “Multifunctional polymer nanocomposites with FRET-based sensing capabilities.” 05/2018–01/2019

    5.2018 Mayo Clinic Arizona – “Alliance Fellow in the Mayo Clinic and Arizona State University Alliance for Health Care Faculty Summer Residency program.” Co-PI: Vijay Singh (Mayo Clinic of Arizona), 05/29/2018–07/28/2018

    6.2018 NSF CBET–“Fouling resistant, freestanding zwitterionic polysulfones for osmotically driven membrane processes” 09/01/2018–08/31/2021

    7.2018 NASA ECF Award “Scalable Membrane-supported IL CO2 capture and removal systems” 10/1/2018–9/30/2021

    8.2019 NSF CAREER Award “CAREER: Using electrostatic interactions to guide microstructure and mechanical properties in block polyelectrolytes” 09/01/2019–08/31/2024

    9.2019 ASU-Mayo Seed Grant - "Interaction between pancreatic triglyceride lipase (PNLIP) and its selective inhibitor." Co-PI: Vijay Singh (Mayo Clinic AZ) 01/01/2019-12/31/2019

    10.ARPA-E 2018 OPEN “Mining the Air for Fuels and Fine Chemicals” Co-PIs: Klaus Lackner (ASU), Benny Freeman (UT-Austin), Jennifer Wade (NAU) 08/13/2019–08/12/2022

    11.2019 Defense University Research Instrumentation Program (DURIP) – “Enabling microscopic analysis of microstructured soft materials”  Co-PIs: Lenore Dai, Brent Nannenga, César Torres, 02/28/2019 – 02/27/2020

    12.2021 Watts “Understanding the mechanism of the Watts OneFlow Media” 1/1/2021–06/30/2021

    Co-PI

    1.2016 DOI USBR DWPR – “Modeling and Experiments of Advanced Hybrid Pervaporation Membrane Processes to Minimize Concentrate Volume for Inland Brackish Water Desalination.” PI: Mary Laura Lind; Co-PI: Shane Walker (UTEP) 09/01/2016–09/30/2017

    2.2018 Iowa State University (DOD-AMC) – “.” PI: Reza Montazami (ISU); Co-PIs: Lisa Hall (OSU); Matthew Green; 08/01/2018–07/31/2021

    3.2019 Defense University Research Instrumentation Program (DURIP) – “Enabling 3D Fluorescence Imaging Under Anaerobic Environments” PI: César Torres; Co-PIs: Matthew Green, Rosa Krajmalnik-Brown, James Adams, Bruce Rittman, Brent Nannenga 05/01/2019–04/30/2020

    4.2019 DOI USBR DWPR – “Advancing pervaporation for the treatment of concentrates in inland desalination” PI: François Perrault; Co-PIs: Matthew Green, Mary Laura Lind, Rafael Verduzco (Rice University), Shane Walker (UTEP) 10/01/2019–03/31/2021

    5.2019 NSF MRI – “MRI: Acquisition of an energy-filtering, direct electron detector for advanced soft and hard materials research with in situ transmission electron microscopy” PI: Peter Crozier; ~38 Co-PIs and senior personnel; 9/1/2019–08/31/2021

    6.2020 NSF IRES – “IRES Track I: Exploring Biobased Plastics and Materials through Collaborative Research in Japan” PI: David Nielsen; Co-PIs: Matthew Green, Abhinav Acharya, Arul Varman, Xuan Wang, Thiagarajan Soundappan (Navajo Technical University), 9/1/2020–8/31/2023

    7.2020 DOE EERE – “ASU’s DAC polymer-enhanced cyanobacterial bioproductivity (AUDACity)” PI: Wim Vermaas; Co-PIs: Matthew Green, Klaus Lackner, John McGowen, Jason Quinn (Colorado State University) 10/1/2020–9/30/2023

    8.2021 ASU LightWorks – “Fossil-free fuel synthesis strategies using CO2 from air” PI: Gary Moore; Co-PIs: Matthew Green, Klaus Lackner, 12/1/2020–6/30/2021

    9.2021 Standard Industries – “Potential Concepts for Materials CO2 Capture” PI: Klaus Lackner; Co-PIs: Matthew Green, 3/1/2021–6/30/2021

Fall 2021
Course NumberCourse Title
CHE 492Honors Directed Study
CHE 592Research
CHE 599Thesis
CHE 792Research
CHE 799Dissertation
Summer 2021
Course NumberCourse Title
CHE 792Research
CHE 799Dissertation
Spring 2021
Course NumberCourse Title
CHE 493Honors Thesis
CHE 499Individualized Instruction
CHE 592Research
CHE 593Applied Project
CHE 599Thesis
CHE 792Research
CHE 795Continuing Registration
Fall 2020
Course NumberCourse Title
CHE 468Polymer Principles&Processing
CHE 492Honors Directed Study
CHE 493Honors Thesis
CHE 568Polymer Principles&Processing
CHE 592Research
CHE 593Applied Project
CHE 599Thesis
CHE 792Research
CHE 799Dissertation
Summer 2020
Course NumberCourse Title
CHE 593Applied Project
CHE 792Research
Spring 2020
Course NumberCourse Title
CHE 492Honors Directed Study
CHE 493Honors Thesis
CHE 499Individualized Instruction
CHE 592Research
CHE 593Applied Project
CHE 599Thesis
CHE 792Research
CHE 795Continuing Registration
Fall 2019
Course NumberCourse Title
ASU 101-CHEThe ASU Experience
CHE 492Honors Directed Study
CHE 493Honors Thesis
CHE 494Special Topics
CHM 494Special Topics
CHE 592Research
CHE 593Applied Project
CHE 595Continuing Registration
CHE 598Special Topics
CHM 598Special Topics
CHE 599Thesis
CHE 792Research
CHE 799Dissertation
Summer 2019
Course NumberCourse Title
CHE 593Applied Project
CHE 595Continuing Registration
CHE 792Research
CHE 795Continuing Registration
Spring 2019
Course NumberCourse Title
CHE 492Honors Directed Study
CHE 493Honors Thesis
CHE 592Research
CHE 593Applied Project
CHE 599Thesis
CHE 792Research
CHE 795Continuing Registration
Fall 2018
Course NumberCourse Title
CHE 342Intro Applied Chem Thermodyn
CHE 492Honors Directed Study
CHE 493Honors Thesis
CHE 494Special Topics
CHM 494Special Topics
CHE 592Research
CHE 593Applied Project
CHE 595Continuing Registration
MSE 598Special Topics
CHM 598Special Topics
CHE 598Special Topics
CHE 599Thesis
CHE 792Research
CHE 799Dissertation
Summer 2018
Course NumberCourse Title
CHE 593Applied Project
CHE 595Continuing Registration
Spring 2018
Course NumberCourse Title
CHE 492Honors Directed Study
CHE 493Honors Thesis
CHE 591Seminar
CHE 592Research
CHE 593Applied Project
CHE 599Thesis
CHE 792Research
Fall 2017
Course NumberCourse Title
CHE 342Intro Applied Chem Thermodyn
CHE 492Honors Directed Study
CHE 494Special Topics
CHE 591Seminar
CHE 592Research
CHE 593Applied Project
CHE 595Continuing Registration
CHE 598Special Topics
CHE 599Thesis
CHE 792Research
Summer 2017
Course NumberCourse Title
CHE 593Applied Project
CHE 595Continuing Registration
CHE 599Thesis
Spring 2017
Course NumberCourse Title
CHE 493Honors Thesis
CHE 591Seminar
CHE 592Research
CHE 593Applied Project
CHE 599Thesis
CHE 792Research
Honors / Awards: 
  1. Included in Polymer Chemistry’s 2021 Pioneering Investigators Special Issue
  2. 2020 Scialog Fellow for Negative Emissions Science
  3. Included in Journal of Materials Chemistry C’s 2020 Emerging Investigators Special Issue
  4. 2019 NSF CAREER Award
  5. Included in Industrial & Engineering Chemistry Research’s Special Issue on the 2019 Class of Influential Researchers
  6. 2018 NASA Early Career Faculty Award
  7. Selected as a Mayo Clinic-ASU Alliance Fellow in the 2018 Mayo Clinic and ASU Alliance for Health Care Summer Residency Program
  8. 2018 Ford Faculty Fellowship
  9. 2018 Young Talents Special Issue in Macromolecular Rapid Communications
  10. 2016 North American Membrane Society (NAMS) Young Membrane Scientist Award
  11. Inducted as a member of the American Association for the Advancement of Science (AAAS)/Science Program for Excellence in Science, Spring 2014
  12. Mentee in the AIChE Education Division Future Faculty Mentoring Program, Fall 2013
  13. Hord Fellowship, Fall 2011
  14. Kender Fellowship, Spring 2011
  15. National Science Foundation Macromolecules at the Interface with LifE Sciences (MILES) Integrative Graduate Education and Research Traineeship (IGERT), 2009-2011
  16. Chevron-Phillips Chemical Professional Excellence Travel Award, 2009 & 2010
  17. David H. Jackson/Bostik Findley Inc. Scholarship, 2006
  18. Ellen C. Wheeler Scholarship, 2006
  19. McGrath Award for excellence in polymer chemistry as an undergraduate, 2006
  20. Thomas J. Leivesley Scholarship, 2005, 2006
Editorships: 

Guest editor for 2016 special issue of International Journal of Polymer Science (Hindawi) titled: “Stimuli-responsive polymers: design, synthesis, characterization, and applications.”

Professional Associations: 
  • Association of Environmental Engineering and Science Professors (2016-present)
  • Arizona Water Association (2016-present)
  • North American Membrane Society (2015-present)
  • American Institute for Chemical Engineers (AIChE) (2011-present)
    • Materials Engineering and Science Division (MESD) member
  • American Physical Society (APS) (2014-present)
    • Division of Polymer Physics (DPOLY) member (2014-present)
  • American Chemical Society (2008-present)
    • ACS Polymer Chemistry (POLY) division member
    • ACS Polymer Materials: Science and Engineering (PMSE) division member
Expertise Areas: 
Bioresponsive and Biomimetic Materials
Cell-material Interactions
Food, Water, and Energy Nexus
Materials Science
Nanoscience
Water Treatment Processes